Tricyclohexyl phosphine CAS 2622-14-2

Product Name: Tricyclohexyl phosphine
Synonyms: tricyclohexyl-phosphin;TRICYCLOHEXYLPHOSPHINE, 20 WT. % SOLUTI&;TRICYCLOHEXYLPHOSPHINE, 1M IN TOLUENE;TRICYCLOHEXYLPHOSPHINE, 1M IN TETRAHYDR&;Tricyclohexylphosphine, 20% Toluene Solution;Tricyclohexylphosphine,97%;Tricyclohexylphosphine(20%intoluene),min.88%;tricyclohexylphosphine solution
CAS: 2622-14-2
MF: C18H33P
MW: 280.43
EINECS: 220-069-2
Product Categories: Phosphines;organophosphorus ligand;organophosphine ligand;Achiral Phosphine;Alkyl Phosphine;Ligand;Mitsunobu Reaction;Phosphine Ligands;Phosphines (Mitsunobu Reaction);Synthetic Organic Chemistry;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds
Melting point 81-83 °C(lit.)
Boiling point 110°C
density 0.909 g/mL at 25 °C
Fp 48 °F
storage temp. −20°C
form Solution
color White to off-white
Specific Gravity 0.9
Water Solubility Soluble in most organic solvents. Insoluble in water.
Sensitive Air Sensitive

Melting point 81-83 °C(lit.)
Boiling point 110°C
density 0.909 g/mL at 25 °C
Fp 48 °F
storage temp. −20°C
form Solution
color White to off-white
Specific Gravity 0.9
Water Solubility Soluble in most organic solvents. Insoluble in water.
Sensitive Air Sensitive
Uses
Tricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry.
Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides.
suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides.
This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations.
Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions.
Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.